| Cu1—N1 | 1.9143 (18) | C3—C4 | 1.369 (3) |
| Cu1—N2 | 1.967 (2) | C4—C5 | 1.377 (4) |
| Cu1—N5 | 2.0244 (18) | C4—H4 | 0.9300 |
| Cu1—S1 | 2.4720 (10) | C5—C6 | 1.373 (4) |
| S1—C3 | 1.792 (2) | C5—H5 | 0.9300 |
| S1—S2 | 2.0207 (11) | C6—C7 | 1.361 (4) |
| S2—C8 | 1.787 (2) | C6—H6 | 0.9300 |
| N1—C1 | 1.138 (3) | C7—H7 | 0.9300 |
| N2—C2 | 1.138 (3) | C8—C9 | 1.378 (3) |
| N3—C2i | 1.298 (3) | C9—C10 | 1.360 (3) |
| N3—C1 | 1.303 (3) | C9—H9 | 0.9300 |
| N4—C3 | 1.319 (3) | C10—C11 | 1.375 (3) |
| N4—C7 | 1.337 (3) | C10—H10 | 0.9300 |
| N5—C8 | 1.322 (3) | C11—C12 | 1.359 (3) |
| N5—C12 | 1.356 (3) | C11—H11 | 0.9300 |
| C2—N3ii | 1.298 (3) | C12—H12 | 0.9300 |
| N1—Cu1—N2 | 117.16 (8) | C6—C5—C4 | 118.9 (2) |
| N1—Cu1—N5 | 126.58 (8) | C6—C5—H5 | 120.6 |
| N2—Cu1—N5 | 107.60 (7) | C4—C5—H5 | 120.6 |
| N1—Cu1—S1 | 106.75 (7) | C7—C6—C5 | 118.1 (2) |
| N2—Cu1—S1 | 104.29 (6) | C7—C6—H6 | 121.0 |
| N5—Cu1—S1 | 87.90 (5) | C5—C6—H6 | 121.0 |
| C3—S1—S2 | 105.95 (8) | N4—C7—C6 | 124.6 (2) |
| C3—S1—Cu1 | 102.35 (7) | N4—C7—H7 | 117.7 |
| S2—S1—Cu1 | 98.20 (4) | C6—C7—H7 | 117.7 |
| C8—S2—S1 | 105.52 (8) | N5—C8—C9 | 123.48 (18) |
| C1—N1—Cu1 | 172.06 (19) | N5—C8—S2 | 121.22 (16) |
| C2—N2—Cu1 | 161.63 (17) | C9—C8—S2 | 115.29 (16) |
| C2i—N3—C1 | 120.23 (19) | C10—C9—C8 | 119.1 (2) |
| C3—N4—C7 | 115.9 (2) | C10—C9—H9 | 120.5 |
| C8—N5—C12 | 116.52 (18) | C8—C9—H9 | 120.5 |
| C8—N5—Cu1 | 124.88 (13) | C9—C10—C11 | 118.6 (2) |
| C12—N5—Cu1 | 118.59 (14) | C9—C10—H10 | 120.7 |
| N1—C1—N3 | 173.2 (2) | C11—C10—H10 | 120.7 |
| N2—C2—N3ii | 173.5 (2) | C12—C11—C10 | 119.2 (2) |
| N4—C3—C4 | 124.4 (2) | C12—C11—H11 | 120.4 |
| N4—C3—S1 | 119.92 (16) | C10—C11—H11 | 120.4 |
| C4—C3—S1 | 115.61 (16) | N5—C12—C11 | 123.1 (2) |
| C3—C4—C5 | 118.1 (2) | N5—C12—H12 | 118.5 |
| C3—C4—H4 | 120.9 | C11—C12—H12 | 118.5 |
| C5—C4—H4 | 120.9 |