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. Author manuscript; available in PMC: 2011 Nov 24.
Published in final edited form as: J Am Chem Soc. 2010 Oct 29;132(46):16432–16441. doi: 10.1021/ja1025497

Scheme 1.

Scheme 1

Preparation of the TMG-terminated Film (A) from the Alkenyne 2 and Its Deprotection to the Ethynyl-presenting Film B and Direct CuAAC Reactions with the Azides 3–7 Promoted by Cu+ and the Ligand 10 to Form Films Presenting CF3 (C), OEG (D), Mannose (E), Glucose (F) and Biotin (G)