Table 1.
m/z (charge) | Compound | Relative peak area (%) | |||
---|---|---|---|---|---|
pH 2.0 | pH 4.5 | pH 7.0 | pH 9.0 | ||
975.40 (2+) | Oxytocin “dimer” | ND | 2.4 | 14.5 | 9.7 |
1007.43 (1+) | Oxytocin | 60.6 | 90.6 | 75.8 | 80.3 |
1008.41 (1+) | Deamidated oxytocin | 31.4 | 1.4 | 1.1 | 2.8 |
1009.39 (1+) | Bisdeamidated oxytocin | 8.0 | ND | ND | ND |
1039.37 (1+) | “Trisulfide” oxytocin | ND | 4.8 | 7.0 | 5.7 |
1071.34 (1+) | “Tetrasulfide” oxytocin | ND | 0.9 | 1.7 | 1.4 |
ND not detected