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Examples of Ado• reactions. A) 1,2-rearrangement catalyzed by lysine-2,3-aminomutase.xxv B) Double C-H abstraction and sulfur insertion catalyzed by biotin synthase (BioB).xxvi C) Radical methylation catalyzed by Fom3 in the biosynthesis of fosfomycin.xxvii D) Hydroalkylation of fumarate catalyzed by benzylsuccinate synthase.xxviii
