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. Author manuscript; available in PMC: 2012 Mar 30.
Published in final edited form as: J Am Chem Soc. 2011 Mar 8;133(12):4243–4245. doi: 10.1021/ja200184b

Table 1.

Arylation scope with respect to aryl halidesa

graphic file with name nihms279129u1.jpg
entry aryl halide product yield, %
1 graphic file with name nihms279129t1.jpg graphic file with name nihms279129t2.jpg 78
2 graphic file with name nihms279129t3.jpg graphic file with name nihms279129t4.jpg 61
3 graphic file with name nihms279129t5.jpg graphic file with name nihms279129t6.jpg 77
4 graphic file with name nihms279129t7.jpg graphic file with name nihms279129t8.jpg 81
5 graphic file with name nihms279129t9.jpg graphic file with name nihms279129t10.jpg 62
6 graphic file with name nihms279129t11.jpg graphic file with name nihms279129t12.jpg 75
7 graphic file with name nihms279129t13.jpg graphic file with name nihms279129t14.jpg 73
8 graphic file with name nihms279129t15.jpg graphic file with name nihms279129t16.jpg 60
50b
9 graphic file with name nihms279129t17.jpg graphic file with name nihms279129t18.jpg 85c
a

Aryl halide (1.6–2.5 equiv), benzothiophene (1 equiv), 0.5 mmol scale. Yields are isolated yields. See Supporting Information for details.

b

tert-Butyl-3-bromobenzoate used.

c

Isomer mixture; m/p ratio 1/1.2.