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Perturbation of the aryl iodide.
 | |||
|---|---|---|---|
| Yield [%][a] | |||
| Entry | ArI | 2a | 3a |
| 1[b] | iodobenzene | 29 (<5) | 51 (85) |
| 2 | 1,3-dimethyl-2-iodobenzene | 73 | 24 |
| 3 | 3,5-dimethyl-1-iodobenzene | 52 | 40 |
| 4 | 1-iodo-3,5-bis(trifluoromethyl)benzene | 78 | 12 |
| 5 | 1-iodo-2,4,6-triisopropylbenzene | 87 | 7 |
Yield of combined isolated diastereomers.
Yields in parentheses refer to when 5.0 equivalents of 1 are employed.
