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. Author manuscript; available in PMC: 2012 Mar 23.
Published in final edited form as: J Am Chem Soc. 2011 Mar 2;133(11):3700–3703. doi: 10.1021/ja1065653

Figure 4.

Figure 4

Upper left: Space-filling drawing of [CuI(mCPy)]4·3CH2Cl2 (Model B1) from crystal coordinates. Upper right: ORTEP structure (50%) of the Cu4I4 core of B1 with only the coordinating N atoms of the mCPy ligands shown. Lower: PL spectra of [CuI(mCPy)]∞ (model A), B1, [CuI(mCPy)]4 (model B2), and ground CuI with mCPy (model C) with excitation wavelength of 350 nm.