Table 3.
Substrate scope for enantioselective bromination. Data determined as in Table 1. Results represent the average of 2–3 runs per substrate.
| Entry | Racemic Starting Material | Product | Yield (%) | E.r. |
|---|---|---|---|---|
| 1 | ![]() |
![]() |
80 | 97.0:3.0 |
| 2 | ![]() |
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85 | 97.0:3.0 |
| 3 | ![]() |
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75 | 96.5:3.5 |
| 4 | ![]() |
![]() |
70 | 96.0:4.0 |
| 5 | ![]() |
![]() |
80 | 94.0:6.0 |
| 6 | ![]() |
![]() |
70 | 97.0:3.0 |
| 7 | ![]() |
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65 | 96.5:3.5 |
| 8 | ![]() |
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85 | 87.0:13.0 |
| 9 | ![]() |
![]() |
77* | 85.0:15.0 |
| 10 | ![]() |
![]() |
70 | 95.0:5.0 |
4 equiv of NBP.



















