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. Author manuscript; available in PMC: 2011 Mar 29.
Published in final edited form as: Science. 2010 Jun 4;328(5983):1251–1255. doi: 10.1126/science.1188403

Table 3.

Substrate scope for enantioselective bromination. Data determined as in Table 1. Results represent the average of 2–3 runs per substrate.

Entry Racemic Starting Material Product Yield (%) E.r.
1 graphic file with name nihms282268t13.jpg graphic file with name nihms282268t14.jpg 80 97.0:3.0
2 graphic file with name nihms282268t15.jpg graphic file with name nihms282268t16.jpg 85 97.0:3.0
3 graphic file with name nihms282268t17.jpg graphic file with name nihms282268t18.jpg 75 96.5:3.5
4 graphic file with name nihms282268t19.jpg graphic file with name nihms282268t20.jpg 70 96.0:4.0
5 graphic file with name nihms282268t21.jpg graphic file with name nihms282268t22.jpg 80 94.0:6.0
6 graphic file with name nihms282268t23.jpg graphic file with name nihms282268t24.jpg 70 97.0:3.0
7 graphic file with name nihms282268t25.jpg graphic file with name nihms282268t26.jpg 65 96.5:3.5
8 graphic file with name nihms282268t27.jpg graphic file with name nihms282268t28.jpg 85 87.0:13.0
9 graphic file with name nihms282268t29.jpg graphic file with name nihms282268t30.jpg 77* 85.0:15.0
10 graphic file with name nihms282268t31.jpg graphic file with name nihms282268t32.jpg 70 95.0:5.0
*

4 equiv of NBP.