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. Author manuscript; available in PMC: 2012 Mar 1.
Published in final edited form as: Photochem Photobiol. 2011 Jan 4;87(2):275–283. doi: 10.1111/j.1751-1097.2010.00869.x

Table 1.

Quenching constants for the singlet excited state of PHEO by nucleosides in the presence and absence of CARBOQ.

Guanosine
Adenosine
Inosine
KS-V 103 M−1 kq 1011M−1S−1 KS-V 103 M−1 kq 1011 M−1 S−1 KS-V 103 M−1 kq 1011 M−1 S −1
PHEO 2.3 ± 0.2 4.9 ± 0.2 1.6 ± 0.3 3.4 ± 0.2 1.1 ± 0.2 2.3 ± 0.2
PHEO–CARBOQ mixture 4.1 ± 0.2 8.7 ± 0.3 2.2 ± 0.3 4.7 ± 0.3 1.6 ± 0.2 3.4 ± 0.3
Oxidation potential (V)* 1.29 1.42 1.5

The lifetime of PHEO 4.7 ns (15) in PBS/7.4 was used.

*

Ref. (32,33). PHEO = pheophorbide-a; CARBOQ = carboquone.