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. Author manuscript; available in PMC: 2012 Mar 9.
Published in final edited form as: Chem Rev. 2011 Feb 14;111(3):1417–1492. doi: 10.1021/cr100327p

Table 5.

Synthesis of Exocyclic Alkenes (Suzuki and coworkers, 1992)a

Entry Haloalkene Product Yield (%)
1 graphic file with name nihms273916t18.jpg graphic file with name nihms273916t19.jpg 68
2 graphic file with name nihms273916t20.jpg graphic file with name nihms273916t21.jpg 83
3 graphic file with name nihms273916t22.jpg graphic file with name nihms273916t23.jpg 51
4 graphic file with name nihms273916t24.jpg graphic file with name nihms273916t25.jpg 60
a

Hydroboration was carried out with 9-BBN-H in THF at 0 ºC-rt. for 4 h then cross-coupled intramolecularly in the presence of Pd(dppf)Cl2 (1.5 mol%) and NaOH (3.0 equiv).