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. Author manuscript; available in PMC: 2012 Apr 6.
Published in final edited form as: J Am Chem Soc. 2011 Mar 10;133(13):4975–4983. doi: 10.1021/ja110663u

Table 1.

Parameters used to fit equation 1 to the cumulative residence time distribution accounting for four sub-populations

Population Fused Silica
TMS
PEG(5000)
fi τi (s) fi τi (s) fi τi (s)

A 0.73(3) 0.59(5) 0.81(2) 0.65(3) 0.54(2) 1.18(4)
B 0.19(3) 2.6(3) 0.16(2) 2.9(2) 0.31(1) 5.0(3)
C 0.069(7) 10.6(6) 0.028(3) 13(2) 0.104(6) 20.4(9)
D 0.0135(5) 69(2) 0.004(2) 45(8) 0.0437(8) 109(1)