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. Author manuscript; available in PMC: 2011 Jul 21.
Published in final edited form as: J Am Chem Soc. 2010 Jul 21;132(28):9610–9615. doi: 10.1021/ja907769g

Figure 5.

Figure 5

Arrhenius plots of the observed first-order rate rate constants for the fast phase of decay of the CoII-substrate radical pair states, which were generated by using natural abundance (1H-aminoethanol) substrate. Data from Table 1 for the 1H-substrate radical kobs,f (black solid circles) and for the 2H-substrate radical kobs,f (red solid squares) are shown. The linear fits of the Arrhenius expression for the 1H-substrate radical (black lines) and for the 2H-substrate radical (red lines) are overlaid on the data. The A and Ea values derived from the fitting parameters are collected in Table 2.