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. Author manuscript; available in PMC: 2011 Sep 1.
Published in final edited form as: Nat Chem Biol. 2011 Jan 16;7(3):154–160. doi: 10.1038/nchembio.512

Fig. 3.

Fig. 3

Different patterns for cleaving the Cα-Cβ bond of L-Trp neutral radical 11. The DFT calculation-based, relative free energies (including solvent effect ΔGsol) are in kcal/mol. In Path 1 and Path 2 the energy of 16 + 17 is used as the reference zero energy, whereas in Path 3 the energy of 16 + 20 is used as the reference.