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. Author manuscript; available in PMC: 2011 Sep 1.
Published in final edited form as: Nat Chem Biol. 2011 Jan 16;7(3):154–160. doi: 10.1038/nchembio.512

Scheme 1.

Scheme 1

NosL-catalyzed carbon chain reconstitution of L-Trp shown by labeling patterns and generation of fluorinated MIA analogues. The solid rectangle shows the 13C-labeled carbon atom. D, deuterium. F, fluorine.