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. Author manuscript; available in PMC: 2012 Mar 15.
Published in final edited form as: Inorganica Chim Acta. 2011 Mar 15;368(1):187–193. doi: 10.1016/j.ica.2011.01.002

Table 1.

1H and 195Pt NMR chemical shifts of SeMet complexes

CH3 Hα Hβ Hγ 195Pt
SeMet 2.02 3.84 2.19, 2.24 2.63 N/A
[Pt(dien)(SeMet-Se)]2+ 2.44, 2.43 3.96 2.44 3.09, 2.98 −3420
[Pt(Me4en)(SeMet-Se,N)] R 2.49 3.55 2.36, 2.79 2.91 −3190
[Pt(Me4en)(SeMet-Se,N)] S 2.47 3.55 2.14, 2.87 3.17 −3260
[Pt(en)(SeMet-Se,N)]+ 2.41, 2.43 3.48 2.32, 2.54 3.05, 2.93 −3381, −3393
[Pt(en)(SeMet-Se 2+)2] 2.53, 2.54 3.86 2.25, 2.39 3.07, 3.18 −3910
cis-[Pt(SeMet-Se,N)2] RR 2.55 3.73 2.36, 2.68 2.97, 3.04 −3882
cis-[Pt(SeMet-Se,N)2] RS 2.50, 2.46 3.70, 3.76 2.28, 2.52a a −3837
cis-[Pt(SeMet-Se,N)2] SS 2.49 3.85 2.20, 2.44 3.09a −3815
a

Incomplete assignment due to overlap with other signals