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. Author manuscript; available in PMC: 2012 May 10.
Published in final edited form as: J Am Chem Soc. 2011 Apr 15;133(18):6902–6905. doi: 10.1021/ja200664x

Table 3.

Asymmetric Synthesis of β,β-Disubstituted Cyclic Ketones.a

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a

Conditions: Reactions were performed with phenylboronic acid (0.50 mmol), cycloalkenone (0.25 mmol), Pd(OCOCF3)2 (5 mol%), and ligand 4 (6 mol%) in (ClCH2)2 (1 mL) at 60 °C for 12 h.