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. Author manuscript; available in PMC: 2012 Apr 6.
Published in final edited form as: J Am Chem Soc. 2011 Jan 25;133(6):1702–1705. doi: 10.1021/ja110466q

Figure 3.

Figure 3

(a) Spectral changes of 0.4 mM [LCuII(O2•−)]+ in the presence of 8 mM BNAH at −125°C in MeTHF. The first spectrum recorded (green) is that immediately following O2-bubbling to a solution of [LCuI]+ + BNAH. Inset: pseudo first order kinetics fit from 741 nm data. (b) Plots of kobs as a function of BNAH, BNAD, and BzIMH concentration used to determine second order rate constants.