ORTEP drawing of complex 4. Thermal ellipsoids are drawn at 50% probability, hydrogen atoms are omitted for clarity. Selected bond lengths (Å): Pd–C(1) 2.009(5), Pd–C(25) 2.018(5), Pd– N(1) 2.038(4), Pd–N(15) 2.082(4), Pd–O(1) 2.226(3). Selected bond angles (°): C(19)–Pd–C(25) 91.09(15), C(19)–Pd–N(15) 92.18(16), C(25)–Pd–N(15) 175.68(17), C(19)–Pd–F(1) 91.09(15), C(25)–Pd–F(1) 83.31(16), C(19)–Pd(1)–O(1) 175.74 (16), C(25)–Pd(1)–O(1) 95.15 (16).