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. Author manuscript; available in PMC: 2012 Apr 1.
Published in final edited form as: Coord Chem Rev. 2011 Apr;255(7-8):920–937. doi: 10.1016/j.ccr.2011.01.009

Table 1.

Select metrical parameters for pseudotetrahedral L3CoIII(NR) complexes.

Complex Co-N bond length (Å) N-C bond length (Å) Co-N-C angle (°) Displacement of Co from L3 plane (Å) Ref
[PhBPPh3]Co(Np-tolyl) 1.658(2) 1.367(2) 169.5(1) 1.23 [57]
[PhBPPh3]Co(NtBu) 1.633(2) 1.442(2) 176.7(1) 1.24 [85]
[PhBPiPr3]Co(Np-tolyl) 1.667(2) 1.315(3) 173.2(2) 1.21 [73]
[(TIMENmes)Co(Np-OMeC6H4)][BPh4] 1.675(2) 1.386(4) 168.7(2) 0.90 [58]
(TptBu,Me)Co(NtBu) 1.660(3) 1.449(5) 179.4(3) 1.20 [86]
(TptBu,Me)Co(NAd) 1.655(2) 1.441(3) 178.3(2) 1.196 [87]
[PhB(tBuIm)3]Co(NtBu) 1.659(3) 1.463(5) 179.7(3) 1.17 [59]