Table 2.
Select metrical parameters for pseudotetrahedral L3Fe(NR) complexes.
| Complex | Oxidation State | Fe-N bond length (Å) | N-C bond length (Å) | Fe-N-Cangle(°) | Displacement of Fe from L3 plane (Å) | Ref |
|---|---|---|---|---|---|---|
| {ClFe}3{NtBuFe}(μ3-NtBu)4 | 4+ | 1.635(4) | -- | 178.6(3) | -- | [84] |
| {[PhBPPh3]Fe(NAd)}{NnBu4} | 2+ | 1.651(2) | 1.434(3) | 178.6(1) | 1.24 | [54] |
| [PhBPPh3]Fe(NAd) | 3+ | 1.641(2) | 1.428(3) | 176.3(2) | 1.32 | [54] |
| [PhBPPh3]Fe(Np-tolyl) | 3+ | 1.658(3) | 1.383(3) | 170.0(2) | 1.31 | [53] |
| 1.661(3) | 1.374(3) | 167.3(2) | 1.29 | |||
| [PhBPPh3]Fe(NtBu) | 3+ | 1.635(1) | 1.442(2) | 179.2(1) | 1.29 | [85] |
| [PhBPiPr3]Fe(NAd) | 3+ | 1.638(2) | 1.438(3) | 176.0(2) | 1.27 | [73] |
| [PhBPCH2Cy3]Fe(NAd) | 3+ | 1.622(4) | 1.433(6) | 176.3(3) | 1.24 | [98] |
| [PhB(mesIm)3]Fe(NCPh3) | 3+ | 1.654(3) | 1.473(4) | 177.7(3) | 1.20 | [48] |
| [PhB(PtBu)2(pz)]Fe(NAd) | 3+ | 1.626(8) | 1.33(3) | 176(1) | 1.27 | [55] |
| 1.634(8) | 1.59(3) | 170(1) | 1.26 | |||
| {[PhB(PtBu)2(pz)]Fe(NAd)}{BArF24} | 4+ | 1.61(1) | 1.44(2) | 174(1) | 1.13 | [55] |
| [PhB(PtBu)2(pzMe,Me)]Fe(NAd) | 3+ | 1.647(8) | 1.45(1) | 172.2(6) | 1.22 | [55] |
| 1.652(8) | 1.44(1) | 172.4(6) | 1.23 | |||
| {[PhB(PtBu)2(pzMe,Me)]Fe(NAd)}{BArF24} | 4+ | 1.634(4) | 1.456(6) | 176.3(3) | 1.11 | [55] |
| [PhB(mesIm)3]Fe(NAd) | 3+ | 1.625(5) | 1.441(7) | 177.0(3) | 1.13 | [50] |
| {[PhB(mesIm)3]Fe(NAd)}{BPh4} | 4+ | 1.618(3) | 1.439(5) | 176.8(3) | 1.15 | [50] |