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. Author manuscript; available in PMC: 2012 Apr 6.
Published in final edited form as: J Am Chem Soc. 2011 Jan 19;133(6):1738–1741. doi: 10.1021/ja111163u

Table 1.

Scope for organocatalytic cycloketone α-fluorination.a,b

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a

Isolated yield.

b

Determined by chiral GC-FID, absolute configuration determined by chemical correlation, X-ray analysis or by analogy.

c

GC yield.

d

Regioselectivity.

e

Using 20 mol % 35·TCA.

f

Using 10 mol % epi-34·TCA.

g

The difluorination product was obtained in 34% yield.