Table 1. Selected Bond Lengths (Å) and Angles (°) for [Mn(CH3CN)2(OTf)2]n, trans-[Mn(C5H5N)4(Otf)2], and [Mn(H2O)6](Otf)2.
| [Mn(CH3CN)2(OTf)2]n | [Mn(C5H5N)4(OTf)2] | [Mn(H2O)6](OTf)2 | |||
|---|---|---|---|---|---|
| Mn-O(1) | 2.1755(7) | Mn-O1 | 2.1577(13) | Mn-O(1W) | 2.1624(10) |
| Mn-O(1)#3a | 2.1755(7) | Mn-O4 | 2.1583(13) | Mn-O(1W)#4 | 2.1625(10) |
| Mn-O(2)#1 | 2.1673(8) | Mn-N1 | 2.2725(16) | Mn-O(1W)#5 | 2.1625(10) |
| Mn-O(2)#2 | 2.1673(8) | Mn-N2 | 2.2546(15) | Mn-O(1W)#6 | 2.1625(10) |
| Mn-N(1) | 2.2079(9) | Mn-N3 | 2.2909(15) | Mn-O(2W) | 2.1474(14) |
| Mn-N(1)#3 | 2.2079(9) | Mn-N4 | 2.2533(14) | Mn-O(2W)#4 | 2.1474(14) |
| O(2)#1-Mn-O(2)#2 | 180.00(4) | O1-Mn-O4 | 173.13(6) | O(2W)-Mn-O(2W)#4 | 180.0 |
| O(1)-Mn-O(2)#2 | 90.45(3) | O1-Mn-N1 | 90.07(6) | O(1W)-Mn-O(2W) | 91.73(4) |
| O(1)-Mn-O(2)#1 | 89.55(3) | O4-Mn-N1 | 94.78(6) | O(1W)-Mn-O(2W)#4 | 88.27(4) |
| O(2)#1-Mn-N(1)#3 | 91.13(3) | N1-Mn-N2 | 90.13(5) | O(1W)-Mn-O(1W)#5 | 86.19(7) |
| N(1)-Mn-N(1)#3 | 180.0 | N1-Mn-N3 | 178.81(6) | O(1W)#3-Mn-O(1W)#5 | 93.81(7) |
| O(1)-Mn-O(1)#3 | 180.0 | N1-Mn-N4 | 89.40(5) | O(1W)-Mn-O(1W)#1 | 180.0 |
| C(1)-N(1)-Mn | 153.68(9) | N2-Mn-N4 | 179.53(6) | O(1W)#4-Mn-O(1W)#6 | 180.00(9) |
a
Symmetry transformations used to generate equivalent atoms: #1 x+1,y,z; #2 -x-1,-y,-z-1; #3 -x,-y,-z-1; #4 -x,-y,-z #5 -x,y,-z #6 x,-y,z.