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Structures A and B correspond to the cross-linked core peptides that are predicted to arise from eDNA derived NRPS systems. An inventory of the number and type of tailoring enzymes (or functional group transferases) found in sequenced gene clusters from cultured soil bacteria as well as gene clusters cloned from eDNA is shown. For gene clusters associated with known metabolites, the number of tailoring enzyme derived functional groups found on the encoded metabolite is also shown.
