Table 1.
| ||||
---|---|---|---|---|
entry | azine | ArBr | product | yield (%)a |
1 | 1a | 53 | ||
2 | “ | 1b | 51 | |
3 | “ | 1c | 78 | |
4 | “ | 1d | 70 | |
5 | “ | 1e | 76 | |
6 | “ | 1f | 67 | |
7 | “ | 1g | 0 | |
8 | “ | 1h | 86b | |
9 | “ | 1i | 65b | |
10 | 1j | 73b | ||
11 | “ | 1k | 49c | |
12 | “ | 1l | 24b | |
13 | “ | 1m | 26b | |
14 | “ | 1n | 33b |
Isolated yield of analytically pure product; 0.4 mmol scale in ArBr; 0.8 M absolute concentration in ArBr;
Reaction run at 175 °C and 0.3 M absolute concentration in ArBr;
Reaction run at 165 °C and 0.3 M absolute concentration in ArBr.