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. Author manuscript; available in PMC: 2012 Jun 22.
Published in final edited form as: J Am Chem Soc. 2011 May 26;133(24):9311–9319. doi: 10.1021/ja1110514

Figure 5.

Figure 5

Routes for the conversion of cThz*-P 14 and cThz-P 16 to thiamin phosphate 18. In bacteria lacking TenI, ThiE can catalyze the coupling of the thiazole tautomer 14 and HMP-PP 17 to give 21, which is converted to 18 directly or via intermediate 22.