Table 11.
DcA of Protected α-Hydroxy Allyl Vinyl Carbonates
![]() | |||||
---|---|---|---|---|---|
entry | SM | n | yield (%) | dr | ee (major) |
1 | 39 | 1 | quant. | 2.5:1 | 92% |
2 | 38 | 2 | quant. | 11:1 | >99% |
3 | 39 | 2 | quant. | 11:1 | >99% |
4 | 38 | 3 | quant. | 50:1 | >99% |
5 | 39 | 3 | 30% | 50:1 | >99% |
DcA of Protected α-Hydroxy Allyl Vinyl Carbonates
![]() | |||||
---|---|---|---|---|---|
entry | SM | n | yield (%) | dr | ee (major) |
1 | 39 | 1 | quant. | 2.5:1 | 92% |
2 | 38 | 2 | quant. | 11:1 | >99% |
3 | 39 | 2 | quant. | 11:1 | >99% |
4 | 38 | 3 | quant. | 50:1 | >99% |
5 | 39 | 3 | 30% | 50:1 | >99% |