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. 2011 May 6;5:22. doi: 10.1186/1752-153X-5-22

Table 11.

Activation parameters for the hydration of carbon dioxide in water

Reaction a Inline graphic ΔuTS / kcal mol-1 σ Inline graphic
CO2 + H2O 30
(16.35)
1.50 102
(2.61 103)
35.95
(9.70)
5.76 10-2
(2.38 10-2)
0.49
(0.10)
CO2 + OH- 1 1.95 1015
(4.49 1014)
15.33
(0.13)
1.02 10-1
(1.27 10-2)
0.038
(3.28 10-4)

Standard deviations are given in parentheses.