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Activation parameters for the solvolysis of methyldiphenylsulfonium ion in H2O and EtOH
| Solvent | a |  |
ΔuTS / kcal mol-1 | σ |  |
|---|---|---|---|---|---|
| H2O | 1 | 3.36 1010 (1.22 1010) |
26.51 (0.22) |
4.04 10-2 (1.06 10-2) |
2.57 10-2 (2.13 10-4) |
| EtOH | 77 (13.75) |
1.00 10-2 (3.48 10-2) |
72.51 (8.76) |
1.01 10-2 (4.98 10-3) |
0.69 (3.87 10-2) |
Standard deviations are given in parentheses.
