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. 2011 May 3;400(10):3473–3479. doi: 10.1007/s00216-011-5050-z

Fig. 2.

Fig. 2

Post-column infusion chromatograms. Indicated by the arrows are the retention times of OSC t R1 = 1.88 min and OS t R2 = 3.20 min. The major drops in the XIC signal (for OS m/z 313+ → 225 and OSC m/z 285+ → 138) are due to ion suppression of eluting matrix compounds at the beginning of the gradient and due to a sudden change in solvent composition after ∼3.4 min