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. 2011 May 19;133(25):9863–9871. doi: 10.1021/ja2019367

Table 3. (top) Driving forces (ΔG°),a Reorganization Energies (λ), and Electronic Coupling Values (V) for Charge Separation in PnC60 Obtained from Individual Fits of the Curves in Figure 6; (bottom) Reorganization Energies and Electronic Coupling Values for Charge Separation in PnC60 Obtained by Treating the Electronic Coupling as a Global Parameter.

  P1C60 P2C60 P3C60 P4C60 P6C60
ΔG°/eVa –0.58 –0.38 –0.31 –0.28 –0.25
λ/eV 0.85 0.63 0.66 0.73 0.68
V/cm–1 44 21 31 43 39
  P1C60 P2C60 P3C60 P4C60 P6C60
λ/eV 0.78 0.74 0.69 0.69 0.66
V/cm–1 34 34 34 34 34
a

ΔG° values for P1C60, P2C60, and P4C60 were taken from ref (44). The values for P3C60 and P6C60 were obtained by interpolation and extrapolation of a plot of ΔG° vs 1/n, where n is the number of porphyrin units.