Table 2.

Perfluoroalkylation Scope with Respect to R_FH^a

entry	1H-polyfluoroalkane	product	yield
1b	CF3H		51
2	C2F5H		96
3	CF3CF2CF2H		83
4	CF3(CF2)4CF2H		87
5	CF3(CF2)8CF2H		81
6	H(CF2)6H		79
7	H(CF2)8H		84
8c	H(CF2)8H		63
9	H(CF2)4Cl		94
10d	H(CF2)4CONC5H10		62

^aTMP₂Zn (0.75 mmol), R_FH (1.5–5 mmol), DMPU, ArI (0.5 mmol), phenanthroline (0.1 mmol), CuCl (0.05 mmol), 90 °C.

^bPhenanthroline (1 mmol).

^cTMP₂Zn (1 mmol), R_FH (0.5 mmol), DMPU, ArI (4 mmol), phenanthroline (0.1 mmol) and CuCl (0.05 mmol).

^dTMP₂Zn (0.5 mmol), R_FH (0.5 mmol), DMPU, ArI (1.5 mmol), phenanthroline (0.1 mmol) and CuCl (0.05 mmol).