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. Author manuscript; available in PMC: 2011 Jul 7.
Published in final edited form as: Chem Commun (Camb). 2007 Jul 3;(43):4441–4449. doi: 10.1039/b707737h

Table 3.

Catalytic reductive coupling reactions directed by a remote alkenea

enyne aldehyde product yield
1 graphic file with name nihms-308281-t0007.jpg graphic file with name nihms-308281-t0008.jpg graphic file with name nihms-308281-t0009.jpg 69%
2 4 graphic file with name nihms-308281-t0010.jpg graphic file with name nihms-308281-t0011.jpg 58%
3 4 graphic file with name nihms-308281-t0012.jpg graphic file with name nihms-308281-t0013.jpg 60%
4 graphic file with name nihms-308281-t0014.jpg graphic file with name nihms-308281-t0015.jpg graphic file with name nihms-308281-t0016.jpg 64%
5 graphic file with name nihms-308281-t0017.jpg graphic file with name nihms-308281-t0018.jpg graphic file with name nihms-308281-t0019.jpg 62%
6 graphic file with name nihms-308281-t0020.jpg graphic file with name nihms-308281-t0021.jpg graphic file with name nihms-308281-t0022.jpg 60%
7 graphic file with name nihms-308281-t0023.jpg graphic file with name nihms-308281-t0024.jpg graphic file with name nihms-308281-t0025.jpg 62%
8 graphic file with name nihms-308281-t0026.jpg graphic file with name nihms-308281-t0027.jpg graphic file with name nihms-308281-t0028.jpg 68%
a

See eq 9, Table 2 for representative reaction. R1 = (CH2)3CH=CH2. R2 = CH2CH=CH2. Regioselectivity > 95:5 in all cases, determined by 1H NMR and/or GC.