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Solvent screen for cross-metathesis of 5 with 1 at RT.a
| Substrate | Solvent | Time [h] | Conv.b [%] | Zb [%] |
|---|---|---|---|---|
| MeCN | 3 (28) | 19 (76) | 94 (91) | |
| MeOH | 3 (28) | 49 (87) | 88 (75) | |
| EtOH | 3 (28) | 50 (86) | 89 (76) | |
| C6H6 | 3 (21) | 13 (77) | >95 (84) | |
| methyl undecenoate (5) | Et2O | 3 (7) | 50 (85) | 93 (73) |
| DMF | 3 (21) | 44 (77) | 92 (87) | |
| CH2Cl2 | 3 (21) | 35 (81) | 93 (85) | |
| (CF3)2CHOH | 3 (28) | 0 (0) | - | |
| diglyme | 3 (28) | 31 (81) | 95 (80) |
2 mol% catalyst in solvent (2.25 M in substrate) at 25 °C.
Measured by 1H NMR Spectroscopy.
