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. 2011 Jun 9;4(2):110–115. doi: 10.1080/19393210.2011.561933

Table 1.

MS/MS parameters for detection of trichothecenes in MRM mode.

Analyte Precursor ion (m/z) Product ion (m/z) Declustering potential (V) Collision energy (eV) Ion ratio (Q/q)
T-2 489.2 [M + Na]+ 245.1 (Q) 37
489.2 [M + Na]+ 387.3 (q) 96 27 0.60
489.2 [M + Na]+ 327.1 (q) 29 0.34
HT-2 446.9 [M + Na]+ 345.2 (Q) 23
446.9 [M + Na]+ 285.1 (q) 71 29 0.67
446.9 [M + Na]+ 159.0 (q) 37 0.03
13C-T-2 513.2 [M + Na]+ 406.2 (Q) 29
513.2 [M + Na]+ 260.2 (q) 61 31 0.75
513.2 [M + Na]+ 138.2 (q) 99 0.24

Note: Q: transition used for quantification (quantifier); q: transition used for confirmation (qualifier).