Skip to main content
. Author manuscript; available in PMC: 2012 Aug 3.
Published in final edited form as: J Am Chem Soc. 2011 Jul 12;133(30):11488–11491. doi: 10.1021/ja204997c

Figure 1.

Figure 1

Steady-state phosphorescence spectrum of ZIr2 in the absence (a) and presence (b) of CuCl2. Time-resolved phosphorescence spectrum of ZIr2 in the absence (c) and presence (d) of CuCl2 (λex = 342 nm). Conditions: 10 μM ZIr2 for steady-state spectra and 20 μM ZIr2 for time-resolved spectra in pH 7.0 buffer (25 mM PIPES containing <2 vol % of DMSO). Black diagonal lines in (a) and (b) are harmonics of the excitation beam.