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. Author manuscript; available in PMC: 2012 Jul 13.
Published in final edited form as: J Am Chem Soc. 2011 Jun 17;133(27):10568–10581. doi: 10.1021/ja2021312

Figure 1.

Figure 1

Stick figure representation of the X-ray crystal structure of [Fe2(PIM)(Ph3CCO2)2] (1). Solvent molecules and hydrogen atoms are omitted for clarity. Color scheme: iron, orange; carbon, gray; nitrogen, blue; oxygen, red; sulfur, yellow. Selected bond distances (Å) and angles (Deg): Fe(1)–Fe(2) = 3.6100(6); Fe(1)–N(1) = 2.049(2); Fe(1)–O(2) = 1.878(2); Fe(1)–O(7) = 1.999(2); Fe(1)–O(8) = 2.016(2); Fe(2)–N(2) = 2.039(2); Fe(2)–O(1) = 1.892(2); Fe(2)–O(7) = 2.254(2); Fe(2)–O(6) = 2.153(2); Fe(2)–O(9) = 2.024(2); O(2)–Fe(1)–N(1) = 92.49(8); O(1)– Fe(2)–N(2) = 92.38(8); O(7)–Fe(1)–O(8) = 103.72(8); O(7)–Fe(2)–O(9) = 89.14(7). A thermal ellipsoid ortep diagram of 1 is provided in Figure S13.