Table 10.
Methyl vinyl ketone and cyclopentadiene Diels-Alder cycloaddition activation barriers a
![]() | |
|---|---|
| catalyst | activation barrier |
| uncatalyzed | 19.0 |
| (H2O)2 | 18.5 |
| thiourea catalyst | 17.0 |
Gas phase, B3LYP/6-31+G(d, p)//AM1
Methyl vinyl ketone and cyclopentadiene Diels-Alder cycloaddition activation barriers a
![]() | |
|---|---|
| catalyst | activation barrier |
| uncatalyzed | 19.0 |
| (H2O)2 | 18.5 |
| thiourea catalyst | 17.0 |
Gas phase, B3LYP/6-31+G(d, p)//AM1