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. Author manuscript; available in PMC: 2012 Jul 15.
Published in final edited form as: Org Lett. 2011 Jun 21;13(14):3746–3749. doi: 10.1021/ol2014347

Table 2.

Synthesis of Pyrroles via Rh-Catalyzed Transannulation of N-Tosyltriazoles with Terminal Alkynesa

graphic file with name nihms306091u3.jpg
no. product yield (%)b
1 graphic file with name nihms306091t1.jpg4a 67
2 graphic file with name nihms306091t2.jpg4b 97
3 graphic file with name nihms306091t3.jpg4c 79
4 graphic file with name nihms306091t4.jpg4d 51
5 graphic file with name nihms306091t5.jpg4e 52
6 graphic file with name nihms306091t6.jpg4f 52
7 graphic file with name nihms306091t7.jpg4g 54
8 graphic file with name nihms306091t8.jpg4h 66
9 graphic file with name nihms306091t9.jpg4i 74
10 graphic file with name nihms306091t10.jpg4j 94
11 graphic file with name nihms306091t11.jpg4k 58
12 graphic file with name nihms306091t12.jpg4l 72
13 graphic file with name nihms306091t13.jpg4m 46
14 graphic file with name nihms306091t14.jpg4n 65
15 graphic file with name nihms306091t15.jpg4o 60
16 graphic file with name nihms306091t16.jpg4p 81
17 graphic file with name nihms306091t17.jpg4q 77
18 graphic file with name nihms306091t18.jpg4r 87
19 graphic file with name nihms306091t19.jpg4s 54
20 graphic file with name nihms306091t20.jpg4t 70
21 graphic file with name nihms306091t21.jpg4u 99
22 graphic file with name nihms306091t22.jpg4v 86
23 graphic file with name nihms306091t23.jpg4w 44
24 graphic file with name nihms306091t24.jpg4x 57
25 graphic file with name nihms306091t25.jpg4y 46
26 graphic file with name nihms306091t26.jpg4z 54
a

All reactions were performed in 0.2 mmol scale;

b

Isolated yield; For more information see: Supporting Information (SI).