Table 2.
Synthesis of Pyrroles via Rh-Catalyzed Transannulation of N-Tosyltriazoles with Terminal Alkynesa
![]() | ||
---|---|---|
no. | product | yield (%)b |
1 |
![]() |
67 |
2 |
![]() |
97 |
3 |
![]() |
79 |
4 |
![]() |
51 |
5 |
![]() |
52 |
6 |
![]() |
52 |
7 |
![]() |
54 |
8 |
![]() |
66 |
9 |
![]() |
74 |
10 |
![]() |
94 |
11 |
![]() |
58 |
12 |
![]() |
72 |
13 |
![]() |
46 |
14 |
![]() |
65 |
15 |
![]() |
60 |
16 |
![]() |
81 |
17 |
![]() |
77 |
18 |
![]() |
87 |
19 |
![]() |
54 |
20 |
![]() |
70 |
21 |
![]() |
99 |
22 |
![]() |
86 |
23 |
![]() |
44 |
24 |
![]() |
57 |
25 |
![]() |
46 |
26 |
![]() |
54 |
All reactions were performed in 0.2 mmol scale;
Isolated yield; For more information see: Supporting Information (SI).