Structure of [Rh(cod)(L)2]OTf (L = the acetonide analogue of AP-I) determined by X-ray diffraction reveals C2-symmetric arrangement. The figure graphics are depictions of crystallographic data imported into ChemDraw Ultra 9.0. For clarity, the following substructures were omitted. Top view: methyl groups and triflate ion. Front view: methyl groups, triflate ion and 1,5-cyclooctadiene. Side view: methyl groups, triflate ion, dioxolane rings and phosphonite oxygen atoms.