Table 3.

Dihedral angles along the edges of the coordination polyhedra [°] of the lanthanide complexes with TREN-1,2-HOIQO (1). Shape measure SM_Gd (deviation relative to the gadolinium complex).

Edge	La	Ce[a]	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu
O7-O8	55.07	55.68	56.25	56.68	57.31	57.75	57.94	58.37	58.77	58.70	58.85	59.35	59.72	60.10
O7-O5	41.41	41.56	41.77	42.10	42.00	42.24	42.42	42.09	42.36	42.54	42.75	42.31	43.00	41.60
O7-O6	49.04	48.85	49.16	49.02	49.25	49.54	49.40	49.45	49.51	49.18	49.02	49.47	48.91	50.19
O7-O10	56.74	57.09	57.40	57.55	57.88	57.89	57.86	57.90	58.21	58.17	58.30	58.38	59.55	57.81
O7-O9	47.45	46.36	45.77	45.51	44.62	43.87	43.60	43.44	42.49	42.23	42.41	42.03	40.98	41.47
O6-O10	61.63	61.31	61.04	60.82	60.79	60.78	61.22	60.70	60.74	60.98	60.80	60.54	60.87	61.31
O9-O10	68.17	69.12	68.39	68.26	68.38	68.31	68.07	67.95	68.35	68.79	68.42	68.37	69.03	68.33
O3-O9	30.36	29.78	30.81	31.32	31.28	31.93	32.46	32.32	32.54	32.67	33.06	33.07	31.99	33.02
O2-O9	40.79	41.52	40.91	41.39	41.47	40.91	41.13	42.01	42.00	42.25	42.33	42.69	43.26	43.33
O2-O8	63.81	63.67	63.64	63.10	63.33	63.25	63.29	62.81	62.97	62.61	62.80	62.40	62.70	62.62
O2-O5	62.25	62.23	62.55	62.98	63.87	64.15	64.18	63.98	64.33	64.58	64.75	64.47	65.26	64.65
O3-O5	13.68	13.98	13.05	13.10	12.47	12.02	11.46	11.93	11.56	11.64	11.57	12.06	11.18	11.71
O2-O3	86.69	87.41	87.47	87.83	88.45	88.63	88.64	89.19	89.63	89.89	89.75	89.33	89.71	89.14
O5-O6	80.45	80.35	80.54	80.37	80.85	81.14	81.17	81.17	81.44	81.28	81.53	81.25	81.25	81.69
O3 -O6	57.05	57.54	57.88	57.78	58.11	58.46	58.73	59.02	59.53	59.43	59.37	59.66	59.67	59.85
O10-O3	72.70	72.39	72.08	71.85	71.41	71.10	70.54	70.02	69.50	69.50	69.21	68.65	68.80	67.86
O9-O8	68.95	68.61	68.48	67.87	67.32	67.16	67.06	66.82	66.48	66.52	66.14	66.11	65.35	65.52
O8-O5	57.52	57.45	57.87	57.78	57.83	57.87	57.83	58.56	58.19	58.03	57.95	58.62	57.91	58.68
SMGd	2.01	1.78	1.44	1.24	0.89	0.70	0	0.65	0.69	0.72	0.74	0.94	1.27	1.26

^[a]Ref. 9.