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. Author manuscript; available in PMC: 2011 Aug 23.
Published in final edited form as: Free Radic Res. 2009 Apr;43(4):329ā€“339. doi: 10.1080/10715760902736283

Table 1.

The properties of Mn porphyhrins: the ability to catalyze dismutation of O2ā€¢āˆ’ (kcat) , the redox ability, i.e. the metal centered redox potential (E1/2), and the lipophilicity as given by the ratio of the compound and solvent path on TLC silica plates (solvent KNO3sat H2O:H2O: acetonitrile= 1:1+8).

Compound logk cat E1/2, mV vs NHE Rf
MnTE-2-PyP5+ a 7.76 +228 0.13
MnTDE-2-ImP5+ b 7.83 +346 0.17
MnTnHex-2-PyP5+ a 7.48 +314 0.57
MnTnOct-2-PyP5+ a 7.71 +367 0.80
a

ref Batinic-Haberle et al, Dalton 2002

b

ref Batinic-Haberle et al Dalton 2004