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. Author manuscript; available in PMC: 2011 Aug 28.

Published in final edited form as: Eur J Chem. 2011 Jun;2(2):130–135. doi: 10.5155/eurjchem.2.2.130-135.405

Table 3.

Specific rates of solvolysis (k) of 1, 2, and 3, in MeOH, EtOH, 70%HFIP (w/w), and 50% HFIP (w/w) at 25.0ºC.

Solvent (%)^a	1, 10⁵k, s⁻¹^b	2, 10⁵k, s⁻¹^c	3, 10⁵k, s⁻¹^d
100% MeOH	210 ± 8	4.19 ± 0.10	695 ± 9
100% EtOH	110 ± 6	1.09 ± 0.04	260 ± 3
70%HFIP (w/w)	2.54 ± 0.09	60.1 ± 2.4	10.5 ± 0.6
50% HFIP (w/w)	35.2 ± 3.1	71 ± 3.0	31.6 ± 0.6

^a,b

See footnotes in Table 1.

^c

Ref. 27.

^d

Ref. 9.