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. Author manuscript; available in PMC: 2012 Sep 7.
Published in final edited form as: J Am Chem Soc. 2011 Aug 16;133(35):13984–14001. doi: 10.1021/ja203733q

Figure 7.

Figure 7

(A) The dependence of fluorescence time course (λex 320 nm, λem 400 nm) on [1]. Conditions: [7] = 10 µM, [Cu(OAc)2·H2O] = 10 µM, and [1] = 0.5–3.5 mM in CH3OH. (B) Plot of lnVint vs. ln[1]. The slope yields the kinetic order of 2-picolylazide 1. Vint: initial observed rate = d[8]/dt (M·s−1).