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(A) The dependence of fluorescence time course (λex 320 nm, λem 400 nm) on [Cu(OAc)2·H2O]. Conditions: [7] = 50 µM, [Cu(OAc)2·H2O] = 0.8–2.5 µM, and [1] = 5 mM in CH3OH. (B) Plot of lnVint vs. ln[Cu(OAc)2·H2O]. The slope yields the kinetic order of Cu(OAc)2·H2O. Vint: initial observed rate = d[8]/dt (M·s−1).
