Skip to main content
. 2011 Jul 22;7:1007–1013. doi: 10.3762/bjoc.7.114

Table 1.

Results of the one-pot Diels–Alder reaction/Au(I)-catalyzed cyclization.

entry diene dienophile product (yield)a
1 graphic file with name Beilstein_J_Org_Chem-07-1007-i001.jpg graphic file with name Beilstein_J_Org_Chem-07-1007-i002.jpg Inline graphic
(93%)
2 19 graphic file with name Beilstein_J_Org_Chem-07-1007-i004.jpg Inline graphic
(51%)
3 graphic file with name Beilstein_J_Org_Chem-07-1007-i006.jpg graphic file with name Beilstein_J_Org_Chem-07-1007-i007.jpg Inline graphic
(88%)
4 20 graphic file with name Beilstein_J_Org_Chem-07-1007-i009.jpg Inline graphic
(50%)
5 graphic file with name Beilstein_J_Org_Chem-07-1007-i011.jpg graphic file with name Beilstein_J_Org_Chem-07-1007-i012.jpg Inline graphic
(81%)
6 21 graphic file with name Beilstein_J_Org_Chem-07-1007-i014.jpg Inline graphic
(78%)
7 graphic file with name Beilstein_J_Org_Chem-07-1007-i016.jpg graphic file with name Beilstein_J_Org_Chem-07-1007-i017.jpg Inline graphic
(77%)
8 22 graphic file with name Beilstein_J_Org_Chem-07-1007-i019.jpg Inline graphic
(48%)
9 graphic file with name Beilstein_J_Org_Chem-07-1007-i021.jpg graphic file with name Beilstein_J_Org_Chem-07-1007-i022.jpg Inline graphic
(56%)

aIsolated yield and dr > 25:1 in all cases.