Table 3.
Selected Bond Distances (A) and Angles (deg) of MoSeLPh • DMSO, MoSeLCOOMe and MoSeLC4H8
| MoSeLPh•DMSO | MoSeLCOOMe | MoSeLC4H8, a | |
|---|---|---|---|
| Mo1–Se1 | 2.2915(5) | 2.2900(5) | 2.3069(5) |
| Mo1–S1 | 2.3552(11) | 2.3637(11) | 2.3517(12) |
| Mo1–S2 | 2.3400(10) | 2.3645(10) | 2.3627(11) |
| Mo1–S3 | 2.3520(13) | 2.3530(13) | 2.3639(11) |
| Mo1–S4 | 2.3452(8) | 2.3636(13) | 2.3618(11) |
| S1–C1 | 1.768(3) | 1.769(4) | 1.786(4) |
| S2–C2 | 1.789(5) | 1.746(4) | 1.770(4) |
| S3–C3 | 1.785(3) | 1.749(6) | 1.772(4) |
| S4–C4 | 1.784(4) | 1.761(5) | 1.765(4) |
| C1–C2 | 1.345(5) | 1.345(6) | 1.331(7) |
| C3–C4 | 1.380(7) | 1.338(7) | 1.338(7) |
| Mo1–4S plane | 0.7976(7) | 0.7933(7) | 0.79(1) |
| Se1–Mo1–S1 | 109.45(3) | 109.78(3) | 110.86(2) |
| Se1–Mo1–S2 | 109.66(3) | 109.78(3) | 107.59(3) |
| Se1–Mo1–S3 | 109.35(3) | 108.80(3) | 113.20(3) |
| Se1–Mo1–S4 | 111.00(3) | 110.96(3) | 106.50(3) |
| S1-Mo1-S2 | 82.09(3) | 82.91(3) | 82.50(4) |
| S1-Mo1-S3 | 141.20(4) | 141.41(4) | 135.94(4) |
| S1-Mo1-S4 | 84.64(3) | 84.33(4) | 85.77(4) |
| S2-Mo1-S3 | 84.56(4) | 83.74(4) | 84.70(3) |
| S2-Mo1-S4 | 139.34(4) | 139.99(4) | 145.90(3) |
| S3-Mo1-S4 | 82.20(3) | 83.06(4) | 81.78(4) |
a
ref. 20