Table 4.

Selected Bond Distances (A) and Angles (deg) of MoOL^Ph, MoOL^COOMe and MoOL^C4H8

	MoOLPh	MoOLCOOMe, a	MoOLC4H8, b
Mo1–O1	1.709(2)	1.686(6)	1.745(6)
Mo1–S1	2.3874(7)	2.380 c	2.418(3)
Mo1–S2	2.3761(7)		2.384(7)
Mo1–S3	2.3824(8)		2.418(5)
Mo1–S4	2.3778(7)		2.39(1)
S1–C1	1.792(2)	1.758 d	1.76(1)
S2–C2	1.782(3)		1.777(8)
S3–C3	1.785(2)		1.81(1)
S4–C4	1.786(3)		1.783(8)
C1–C2	1.345(4)	1.33(1)	1.34(1)
C3–C4	1.369(5)	1.31(1)	1.32(1)
Mo1–4S–plane	0.7871(5)	e	0.76(1)
O1–Mo1–S1	110.45(8)	108.9 f	106.6(4)
O1–Mo1–S2	108.37(7)		106.2(6)
O1–Mo1–S3	110.64(8)		106.5(3)
O1–Mo1–S4	107.04(7)		108.1(4)
S1-Mo1-S2	82.20(2)	83.1(1)	82.4(2)
S1-Mo1-S3	138.89(2)	140.7(1)	146.8(5)
S1-Mo1-S4	86.70(2)	84.3(1)	88.5(4)
S2-Mo1-S3	83.92(2)	85.3(1)	86.7(2)
S2-Mo1-S4	144.57(3)	143.5(1)	145.7(5)
S3-Mo1-S4	82.67(2)	83.0(1)	83.0(4)

^aref. 23,

^bref. 18,

^caverage distance of the four Mo-S bonds,

^daverage distance of the four C-S bonds,

^enot reported,

^faverage angle of the four O1-Mo1-S angles.