. Author manuscript; available in PMC: 2011 Sep 20.

Published in final edited form as: Inorg Chem. 2008 Aug 1;47(17):7535–7544. doi: 10.1021/ic800328g

Table 3.

Summary of photophysical data for H(n,2)-IAM-MOE complexes with Tb(III) and Eu(III) in 0.1 M TRIS buffer at pH = 7.4 (λ_exc = 338 nm).

Complex	Φ_tot (%)	τ_H₂O (ms)	τ_D₂O (ms)	q^†
[Tb(H(2,2)-IAM-MOE)]	56	2.63	3.27	0.1
[Tb(H(3,2)-IAM-MOE)]	39	1.39	1.91	0.7
[Tb(H(4,2)-IAM-MOE)]	52	1.37	1.83	0.6
[Eu(H(2,2)-IAM-MOE)]	0.14	0.650	0.887	0.2
[Eu(H(3,2)-IAM-MOE)]	0.15	0.548	0.694	0.2
[Eu(H(4,2)-IAM-MOE)]	0.58	0.580	0.750	0.2

^†

Calculated using the equations from Ref. ²⁵; q = 5 × (1/τ_H₂O − 1/τ_D₂O − 0.06) for Tb(III), q = 1.2 × (1/τ_H₂O − 1/τ_D₂O − 0.25) for Eu(III).