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. Author manuscript; available in PMC: 2012 Aug 17.
Published in final edited form as: J Am Chem Soc. 2011 Jul 27;133(32):12584–12589. doi: 10.1021/ja206013j

Table 4.

Chemoselectivity of the Intramolecular C—H Oxidation

graphic file with name nihms314706u4.jpg
entry product isolated yielda dr (anti:syn)b
1 graphic file with name nihms314706t4.jpg 8a 74 4:1
2 graphic file with name nihms314706t5.jpg 8b 77 6:1
3 graphic file with name nihms314706t6.jpg 8c 53 7:1
4 graphic file with name nihms314706t7.jpg 8d 72 3:1
5 graphic file with name nihms314706t8.jpg 8e 52 2:1
a

Average of 2 runs at 0.3 mmol.

b

Diastereomeric ratio determined by GC of the crude reaction after workup.