K representations of a proper and a questionable training set. (A) Dopamine cyclic voltammograms of the proper training set. (B) pH change cyclic voltammograms of the proper training set. (C) kDA for the proper training set shown in (A) and (B). (D) kpH for the proper training set shown in (A) and (B). (E) Dopamine cyclic voltammograms of the questionable training set. (F) pH change cyclic voltammograms of the questionable training set. (G) kDA for the questionable training set shown in (E) and (F). (H) kpH for the questionable training set shown in (E) and (F). (I) and (J) show the recalculated kDA and kpH vectors, respectively, for the questionable training set shown in (E) and (F) if the QH-peak is used for pH change quantitation rather than the C-peak. The arrows in (A), (B), (C), (D), (G), and (H) indicate the direction of the voltammetric sweep.